SPECTRO™ BATTERY RAPID-TESTER

"The electric light did not come from the continuous improvement of candles" [Oren Harari];
nor did faster horses lead to modern transportation [Henry Ford].


Spectro uses the method of electrochemical impedance spectroscopy (EIS) to measure battery performance. This technology opens a new frontier in battery testing.

The performance of a starter battery is governed by three symptoms: State-of-charge, CCA and capacity. A battery tester should reveal all three conditions, but here lays the difficulty: A good battery with low SoC performs alike a fully charged battery that is faded.

U.S. patent 7,072,871
U.S. patent 6,778,913

Pushing the boundaries with EIS and artificial intelligence (AI)

Electrochemical Impedance Spectroscopy (EIS) opens a non-invasive way to test batteries. EIS-based characterization has been in use for decades to study aging effects in batteries with manual interpretation. Multi-model EIS now enables State-of-Health (SoH) assessment using Artificial Intelligence (AI).

MODELS

Spectro CA-12 Battery Rapid-Tester

Cadex C7200 Battery Analyzer The Spectro CA-12 provides a complete battery state-of-health (SoH) assessment by evaluating SoC, CCA and capacity over a broad charge range. The CA-12 uses multi-model electrochemical impedance spectroscopy, an exclusive technology by Cadex.

Note: The Spectro CA-12 is currently only available to Original Equipment Manufacturers (OEM) to integrate into warranty and after-market programs.


Part Number: 11-500-0130

Spectro Modular Battery Rapid-Tester

Cadex C7400 Battery Analyzer The Spectro Modular assesses battery State-of-Health (SoH) by multi-model EIS. Test settings are entered on a computing device connecting to the Spectro Modular by the WebApp called Cadex Link.

On completion of the 30 second test, the results are shown on the host and stored in the Spectro Modular with option to upload to the Cadex Cloud.

The Spectro Modular is fitted with a generic matrix to read the capacity, CAA and SoC of starter batteries. With a model-specific matrix, the Spectro device also tests other batteries, including Li-ion architectures.

Part Number: 11-500-0200-00

 

DESCRIPTION

Why do Starter Batteries Fail?

Mechanical A mechanical defect is commonly diagnosed by physical inspection and a voltmeter. Batteries in trucks often fail due to shock and vibration. Plates short and cases crack. Replace the battery.
Heat-fail Heat promotes corrosion that raises the internal resistance and slows cranking. The resulting drop in CCA can be measured with most automotive battery testers. A heat-fail battery does not die suddenly but gets gradually weaker and should be replaced.
Capacity-fade Battery capacity drops unnoticed until the vehicle won’t start for lack of energy. Capacity and CCA readings don’t correlate; CCA can remain high while the capacity drops low gone. Start-stop, comfort-heating, and electric doors hasten capacity fade. A capacity of 40% estimates a remaining battery life of 6–12 months. Replace battery if lower.

Definition of a Starter Battery

SoC: State-of-charge symbolizes the liquid levels as shown on the right.
SoC CCA Capacity
CCA: Cold Cranking Amp governs cranking simulated by a few- flowing tap.
Capacity: Energy storage capability in RC (Reserve capacity) or Ah. Loss is shown as rock buildup.

Capacity is the Leading Health Indicator

To study failure modes, a luxury car maker in Europe tested 175 starter batteries. Mechanical and heat-fail batteries were eliminated before the test. Figure 6 demonstrates the aging trend.

Most batteries pass through the Capacity Line on the left of the green field following the arrow. Very few batteries fail by dropping through the CCA Line.
Battery Aging Trend
Figure 3: Capacity and CCA of 175 aging AGM starter batteries.
Most batteries pass through the Capacity Line; few fail because of low CCA. The test batteries were trunk mounted and driven in a moderate climate.

Test Method: Capacity and CCA were tested according to DIN and IEC standards by an independent lab in Germany.

Evaluating a starter battery on CCA alone passes a faulty battery as good, only to fail on the road on low capacity. Meanwhile, good batteries are replaced in error based on a CCA threshold of 60–65%. CCA alone cannot predict the end of battery life reliably. CCA tends to stay high while the capacity drops predictably. The Figure 7 observes capacity and CCA of 20 aging batteries.
Figure 4: Comparing CCA and capacity of 20 aging batteries.
CCA of all batteries stays above 65% while the capacity of some batteries falls below 40%.

Test Method: CCA was taken with Spectro CA-12; capacity was measured with an Agilent load bank by applying full discharges according to BCI standards.

Test Snapshot

This failure analysis was taken in Europe. Tropical countries have different ratios.

Ratio Cause Diagnostics
48% Capacity-fade Active mass is worn out.
23% Low charge City driving with ancillaries on.
15% No fault found EIS adds depth to estimations.
12% Low CCA Higher % in worm climates.
1.5% Mechanical Shock and vibration.
0.5% Manufacturing defect Most faults are user-induced. 


Testing is Simple

To test a starter battery, select between flooded or AGM and then enter CCA and capacity ratings in reserve capacity (RC) or ampere hours (Ah). The battery should have a minimal state-of-charge of 50%. The non-invasive test takes 15 seconds; the pass/fail threshold using a generic matrix is set to 40% or other setting specified. (Numeric capacity reading is available with a battery-specific matrix.)

Why EIS?

Long test times and manual evaluation restricted this technology to laboratory use in the past.

Multi-model electro-chemical impedance spectroscopy (Spectro™) scans the battery with multiple frequencies and performs complex modeling to obtain capacity and CCA data. Cadex holds a patent on this technology.

Battery testers based on AC conductance only see R1 of the Randle’s model in Figure 8; Spectro™ provides capacity by modelling R2 and C with matrices serving as lookup tables.

Randle's Model
Figure 5: Randle’s model. R1 reflects resistance (CCA); R2 and C evaluate capacity.
Scientists predict that the future of battery testing lays in EIS. Machine learning promises to expand the test range with high actuary. Cadex realizes the importance of battery diagnostics involving capacity and has been pioneering in EIS technologies since 2004.

An analogy of advancement is the x-ray machine invented in 1895. While the X-ray only shows the outlines of a bone; the CAT scan also reveals soft tissues. Spectro™ with EIS provides this added information in a battery to enable accurate state-of-life predictions.

Integrated Solutions

Cloud Connectivity


Battery Aging Trend
Cadex Cloud API

- Spectro Modular retrieves and uploads data and shows result on the host
- Data is stored in secure database hosted on AWS
- REST provides automated access
- Transport Security – HTTPS

Cloud Connectivity

- Central storage for battery model data that
- AI examines aging effects and predicts Remaining Useful Life (RUL)
- Data input and retrieval via REST API.


Pattern Recognition

An EIS scan with the Spectro Modular allows comparing Nyquist plots against a “golden sample” from a known good battery. Deviation in Migration, Charge Transfer and Diffusion reveals unique battery characteristics.

Applications

  • Research Labs: Evaluates cathode and anode materials; compares additives.
  • Manufacturing: Checks batch consistency.
  • Quality Control: Verifies incoming batteries.
  • Environmental: Analyzes performance by temperatures, SoC and storage.
  • Stress Test: Observes capacity loss with abusive conditions; tracks aging.
  • Longevity: Checks cycling-induced wear.
  • Structural Integrity: Detects dendrites, lithium plating and mechanical anomalies.
  • Second Life: Verifies batteries for reuse.
Note: The Nyquist plot also examines liquids.

Battery Matrix



Modern battery rapid-testing shares similarities with face recognition in which a camera takes a multi-dimensional image to identify features and characteristics with artificial intelligence (AI) and machine learning.
Similarly, battery testing with EIS captures the “landscape” of a battery that leads to state-of-health (SoH) assessments with AI and machine learning. The battery landscape is expressed in a matrix serving as reference tables.
Figure 1. Modern battery testing resembles face recognition.





Creating a matrix involves scanning batteries of diverse SoH and measuring the capacity with charge/discharge cycles. The Data Acquisition Unit (DAU) automates the service.  DAU units are be made available by Cadex on request.

Figure 2. The Nyquist plot reflects battery SoH.




Creating a matrix involves scanning batteries of diverse SoH and measuring the capacity with charge/discharge cycles. The Data Acquisition Unit (DAU) automates the service.  DAU units are be made available by Cadex on request.
Figure 3. Data Acquisition Unit (DAU) tests and scans batteries.

SPECS

SYSTEM SPECIFICATIONS

   

Model

Feature

SPECTRO CA-12 

SPECTRO MODULAR

Desription Battery Service Tool designed for Automotive Battery State of Health (SoH) assessment for Warranty and Aftermarket Service Programs. CCA tests alone do not predict end of battery life! Handheld tester with full keyboard, integrated printer and display make it the in-house or compound workhorse for early battery failure detection @ dealers and workshops looking to make preventative maintenance part of their value addeded solution. Compact module controlled by an external tablet or phone. Tests can be initiated by an Oem's global diagnostic warranty /after market program Tablet or phone and results relayed to the Cadex and Customer cloud.
Technology Non-invasive battery diagnostic service tool based on multi-model electrochemical impedance spectroscopy (EIS) .
EIS Scan Freq. EIS Frequency Scanning range 2048-20 Hz 2,048-16Hz
EV Application (2023)   2,048-0.2/0.1Hz
Test Time   30 Seconds <1Min.
EV Application (2023)   <1-2Min.
Application The Service Tool is designed for automotive battery warranty and aftermarket service  programs. 12V 12V
EV Application (2023)   3 - 60V
Ordering Info Part Number 11-500-013x 11-500-0200-00
Test Parameters:    
Complete State Of Health Assessment ( SoH) Includes: Cranking ability, Capacity (RC/Ah) &  High Resistance check YES YES
Capacity ( Ah/RC) Classification; Pass/Fail assessment
(Capacity entry by IEC and SAE norms)
YES YES
Capacity Test Range 27-105Ah/55-210RC 27-150Ah/55-300RC
CCA In AMPS, Percent; Pass/Fail assessment YES YES
CCA test Range: CCA: 300-1200 CCA: 300-1250
High Resistance Test Significantly reduces Charge & Re-Test decisions well below 50% SoC, especially Heat Failed batteries; possible structral integrity issues: welds, fractures YES YES
Battery Under Test Chemistry 12V Flooded, EFB and AGM starter batteries YES YES
3–60V lithium-ion with model-specific battery characterization profiling (Available in 2023) NO YES
Min. SoC for Complete SoH test: State-of-Charge ( SoC)  in percent (%) |Captures Soc Pass/Fail status YES YES
Ability  to measure batteries at low SoC. Reduces “Charge & Re-Test” requirements 50% SoC <50% SoC
Voltage Supported Shown in 3-digit readout 12V 12V
Test Modes Test Mode support for PDI, Dealer, Ports & aftermarket Service Drive/workshops YES YES
Charge & Re-Test decision Dedicated Capacity ( Ah/RC Mins.) assessment further reduces battery “Charge & Re-Test” decisions YES YES
Surface Charge Detect Promps that battery overcharged. Suggests discharging in order to complete SoH assessment. YES YES
Saved Test Results Onboard ~150 ~1000
  Cloud/Destop Can export to Desktop/cloud Aditional optional storage in cloud
Standalone Use Integration with OEM & Aftermarket back end systems. YES YES
Integrated Solution( w/API Support) Seamless integration with OEM Diagnostics or 3rd party Workshop/Fleet Software applications over API NO YES
  Wireless Connectivity with host devices (Tablet/Cell/Desktop) for OEM service/workshop maintenance systems NO YES
Test Messages Good Battery YES YES
Good battery – Recharge YES YES
Replace Battery (Poor RC) YES YES
Replace Battery ( Poor CCA) YES YES
Replace Battery (Poor RC+CCA) YES YES
Replace Battery (High Resistance Detected) YES YES
Charge and Re-test YES YES
Re-test after self-discharge (Surface Charge Detected) YES YES
Temperature Sensor Degree Celsius and Degree Fahrenheit; selectable YES YES
Clamps Field Replaceable, 4 point Kalvin YES YES
Printing capability Standalone / via Host YES (onboard) NO ( via host )
Display Screen YES NO ( via host )
Keypad   YES NO ( via host )
Camera For scanning NO (barcode uploadable) YES (via Host )
VIN Capture   YES YES(Integrated Solution can import in real -time )
Barcode support 1D/2D YES YES (via Host )
Operating System   Embedded Embedded
Rechargable Tester Battery Li-ion battery cell(s) YES ( 18650 cells) YES (21700 cell)
Number of tests between charge: ~150 ~250
Connectivity/Ports   RS232, USB B/G/N Wi-Fi
Bluetooth
Cloud Support/Analytics Connectivity to Cadex Cloud via  Cadex Link (ie.Web-App) NO Optional
Cadex Link (Android & Windows Support) NO YES
Software upgrade Via Serial Connection (RS232-USB to desktop/Wi-Fi) YES NO
OTA (Over the Air ) Software updates or USC-C to Wifi NO YES
Physical Dimensions D X W X H (mm/Inch/Kg/Lb ) D:172mm(6.77"") W:275mm (10.83"") H:117mm(4.61"")
Wt: 1.58kg (3.5Lb)
D:182mm(7.16"") W:96mm (3.78"") H:47mm(1.85"")
Wt: 430g (.94lb)
Total. w/case: 1.46Kg/3.2lbs 
Power 110–240VAC, 50–60Hz AC power supply YES YES
USB-C NO YES
Environment Temperature:  Humidity: 10–80% 0-40C -10℃ to +45℃ (14°F to 113°F)
Short-Term (up to 30 days) at –20℃ to +30℃ (–4° to 86°F) Humidity: non-condensing YES YES
Long-Term (1-3 months +)  at –20℃ to +25℃ (–4° to 77°F) Humidity: non-condensing YES YES
Approval Tested and approved to comply with: UL3101, CSA 1010, EN61010 EMI/
EMC: FCC part 15 Class A, EN55011
Level A, EN61000-6-3:2001 for EMC
CSA/UL/CE standards. RoHS. REACH, RED,WEEE, ISTA 3A, IP52 and FCC Type A compliant
Warranty Cadex warrants the device against defective materials and workmanship from the original purchase date 2 years 2 years
The cable and clamp carries a  warranty peroid of: 1 year 1 year
Internal battery Warranty  2 years 2 years
Patents U.S. PATENTS:  6,778,913; 7,072,871; 10,302,709 YES YES
* Specifications subject to change

Accessories

CA-12 A+ Battery Clamps Cable for Hyundai

CA-12 A+ Battery Clamps Cable for Hyundai

Part Number: 17-797-0368-00

Product Description
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Dimensions (packaged): 27 x 16 x 10 cm


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CA-12 A+ Battery Clamps Cable for KIA

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Part Number: 17-070-1016-00

Product Description
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CA-12 A+ Battery Pack

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Product Description
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CA-12 A+ AC Adapter Kit (NA power cord)

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Part Number: 92-480-0003-00

Product Description
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CA-12 A+ Calibration Shunt

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Part Number: 17-797-0061

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Weight: 0.5 kg
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CA-12 A+ Replacement Fuse

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CA-12 A+ Thermal Paper Rolls (Pack of 10)

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Part Number: 89-000-0002

Product Description
Weight: less than 1 kg
Dimensions (Roll): 58mm x 28mm
Dimensions (Pack L x W x H): 148mm x 28mm x 116mm


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INQUIRY

The Spectro Modular is only available to Original Equipment Manufacturers (OEM) to seamlessly integrate into warranty and after-market programs. Product inquiries should be directed to the following Cadex Automotive office locations:
Cadex is continuously advancing Spectro™ in the form of improved battery diagnostics, broader test ranges, new battery types, and the distribution of test results. We are interested in your application and would be pleased to discuss your requirements.
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